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To make DIY clay toothpaste powder you simply need a pure, edible-grade clay like bentonite (you can try one like this). You can get fancy and add in charcoal powder, cinnamon, essential oils ...
It's commonly used as a primary ingredient in face masks for acne-prone skin, and one in particular is gaining traction with dermatologists: bentonite clay. "This is a powder derived from volcanic ...