机理研究中，烯胺的当量转化实验证明了催化过程涉及烯胺中间体，而非烯醇反应。改变硼官能团的种类证实了阴离子形式的BF3K对产率和手性控制的重要性。通过监测反应历程，证实了1,4-二甲氧基萘作为Mediator对反应效率提升的关键作用。自由基捕获和抑制实验证明了反应经历自由基中间体。CV测试表明，烯胺应是电化学中被氧化的活性中间体，而且在1,4-二甲氧基萘的存在下可以观察到显著的催化电流。

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