在有机化学合成中，醛的氧化反应一直是研究和应用的重要课题。Corey-Gilman-Ganem氧化反应自1968年首次被报道以来，以其独特的反应机制和温和的氧化条件赢得了科学界的广泛关注。这种反应不仅为合成羧酸酯提供了有效途径，还展现了醛在合成化学中的重要性。

利用二氧化锰与氰离子在溶剂醇中，温和选择性氧化α,β-不饱和醛得到相应的羧酸酯的反应。此反应最早由Corey团队在1968年首先报道。二氧化锰是一种非常温和的氧化剂可以将烯丙醇氧化为烯丙醛而不发生过氧化，但是在HCN或氰化物存在下，烯丙醛可以转化为氰 ...

Jonah Ottman, Jordyn Sutton; Pine Island: Anne Simpson; Red Wing: Kade Altendorf;: Tyler Crow, Catherine Gilman, Tasman ...

Curtin calmly swished the first two free throws and then a Gilman fan yelled out, “Miss it.” The dynamic guard took the chirp in stride, laughed, shook his head and mouthed “No” before ...

MESSAGE TO CONGRESS. SITTING WITH THE FIRST LADY LAST NIGHT WAS THE FAMILY OF COREY COMPARATOR. HE’S THE MAN WHO WAS SHOT AND KILLED AT PRESIDENT TRUMP’S RALLY LAST JULY, WHEN A GUNMAN OPENED ...

Gilman and Spalding have split many decisions this wrestling season. The Greyhounds won the last match of the dual meet between the two before the Cavaliers went on to capture the Maryland ...

While each of several incoming storm systems stays light, each could cause some slick spots to develop.

Gilman Louie is the co-founder, CEO, and Managing Partner at America’s Frontier Fund and a member of the board of directors at Maxar Corporation. Gilman is a member of the President’s Intelligence ...

Who Is Corey Harrison From Pawn Stars? Corey started working at his father’s store at a young age, wanting to learn everything he could about the pawn business. Eventually, he became the manager ...

"We are thrilled to bring our services to Freehold," said Cory Gilman, CEO of Integrated Electrical Solutions. "Our company is committed to providing exceptional service and exceeding customer ...

Azure Gilman is the deputy editor for the Leadership desk at Fortune, assigning and editing stories about the workplace and the C-suite. Before joining Fortune she worked at VICE News and ABC News.

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